Batteries

The Future of Battery Technology

Published

3 years ago

February 23, 2017

The Battery Series
Part 5: The Future of Battery Technology

The Battery Series is a five-part infographic series that explores what investors need to know about modern battery technology, including raw material supply, demand, and future applications.

Presented by: Nevada Energy Metals, eCobalt Solutions Inc., and Great Lakes Graphite

The Battery Series: The Future of Battery Technology

The Future of Battery Technology

This is the last installment of the Battery Series. For a recap of what has been covered so far, see the evolution of battery technology, the energy problem in context, the reasons behind the surge in lithium-ion demand, and the critical materials needed to make lithium-ion batteries.

There’s no doubt that the lithium-ion battery has been an important catalyst for the green revolution, but there is still much work to be done for a full switch to renewable energy.

The battery technology of the future could:

Make electric cars a no-brainer choice for any driver.
Make grid-scale energy storage solutions cheap and efficient.
Make a full switch to renewable energy more feasible.

Right now, scientists see many upcoming battery innovations that have the promise to do this. However, the road to commercialization is long, arduous, and filled with many unexpected obstacles.

The Near-Term: Improving the Li-Ion

For the foreseeable future, the improvement of battery technology relies on modifications being made to already-existing lithium-ion technology. In fact, experts estimate that lithium-ions will continue to increase capacity by 6-7% annually for a number of years.

Here’s what’s driving those advances:

Efficient Manufacturing

Tesla has already made significant advances in battery design and production through its Gigafactory:

Better engineering and manufacturing processes.
Wider and longer cell design allows more materials packaged into each cell.
New battery cooling system allows to fit more cells into battery pack.

Better Cathodes

Most of the recent advances in lithium-ion energy density have come from manipulating the relative quantities of cobalt, aluminum, manganese, and nickel in the cathodes. By 2020, 75% of batteries are expected to contain cobalt in some capacity.

For scientists, its about finding the materials and crystal structures that can store the maximum amount of ions. The next generation of cathodes may be born from lithium-rich layered oxide materials (LLOs) or similar approaches, such as the nickel-rich variety.

Better Anodes

While most lithium-ion progress to date has come from cathode tinkering, the biggest advances might happen in the anode.

Current graphite anodes can only store one lithium atom for every six carbon atoms – but silicon anodes could store 4.4 lithium atoms for every one silicon atom. That’s a theoretical 10x increase in capacity!

However, the problem with this is well-documented. When silicon houses these lithium ions, it ends up bloating in size up to 400%. This volume change can cause irreversible damage to the anode, making the battery unusable.

To get around this, scientists are looking at a few different solutions.

1. Encasing silicon in a graphene “cage” to prevent cracking after expansion.
2. Using silicon nanowires, which can better handle the volume change.
3. Adding silicon in tiny amounts using existing manufacturing processes – Tesla is rumored to already be doing this.

Solid-State Lithium-Ion

Lastly, a final improvement that is being worked on for the lithium-ion battery is to use a solid-state setup, rather than having liquid electrolytes enabling the ion transfer. This design could increase energy density in the future, but it still has some problems to resolve first, such as ions moving too slowing through the solid electrolyte.

The Long-Term: Beyond the Lithium-ion

Here are some new innovations in the pipeline that could help enable the future of battery technology:

Lithium-Air

Anode: Lithium
Cathode: Porous carbon (Oxygen)
Promise: 10x greater energy density than Li-ion
Problems: Air is not pure enough and would need to be filtered. Lithium and oxygen form peroxide films that produce a barrier, ultimately killing storage capacity. Cycle life is only 50 cycles in lab tests.
Variations: Scientists also trying aluminum-air and sodium-air batteries as well.

Lithium-Sulphur

Anode: Lithium
Cathode: Sulphur, Carbon
Promise: Lighter, cheaper, and more powerful than li-ion
Problems: Volume expansion of up to 80%, causing mechanical stress. Unwanted reactions with electrolytes. Poor conductivity and poor stability at higher temperatures.
Variations: Many different variations exist, including using graphite/graphene, and silicon in the chemistry.

Vanadium Flow Batteries

Catholyte: Vanadium
Anolyte: Vanadium
Promise: Using vanadium ions in different oxidation states to store chemical potential energy at scale. Can be expanded simply by using larger electrolyte tanks.
Problems: Poor energy-to-volume ratio. Very heavy; must be used in stationary applications.
Variations: Scientists are experimenting with other flow battery chemistries as well, such as zinc-bromine.

Battery Series: Conclusion

While the future of battery technology is very exciting, for the near and medium terms, scientists are mainly focused on improving the already-commercialized lithium-ion.

What does the battery market look like 15 to 20 years from now? It’s ultimately hard to say. However, it’s likely that some of these new technologies above will help in leading the charge to a 100% renewable future.

Thanks for taking a look at The Battery Series.

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Batteries

Visualizing Copper’s Role in the Transition to Clean Energy

A clean energy transition is underway as wind, solar, and batteries take center stage. Here’s how copper plays the critical role in these technologies.

Published

8 months ago

May 28, 2019

Nicholas LePan

A future powered by renewables is not in the distant horizon, but rather in its early hours.

This new dawn comes from a global awareness of the environmental impacts of the current energy mix, which relies heavily on fossil fuels and their associated greenhouse gas emissions.

Technologies such as wind, solar, and batteries offer renewable and clean alternatives and are leading the way for the transition to clean energy. However, as with every energy transition, there are not only new technologies, but also new material demands.

Copper: A Key Piece of the Puzzle

This energy transition will be mineral intensive and it will require metals such as nickel, lithium, and cobalt. However, one metal stands out as being particularly important, and that is copper.

Today’s infographic comes to us from the Copper Development Association and outlines the special role of copper in renewable power generation, energy storage, and electric vehicles.

Copper and the Clean Energy Transition

Why Copper?

The red metal has four key properties that make it ideal for the clean energy transition.

Conductivity
Ductility
Efficiency
Recyclability

It is these properties that make copper the critical material for wind and solar technology, energy storage, and electric vehicles.

It’s also why, according to ThinkCopper, the generation of electricity from solar and wind uses four to six times more copper than fossil fuel sources.

Copper in Wind

A three-megawatt wind turbine can contain up to 4.7 tons of copper with 53% of that demand coming from the cable and wiring, 24% from the turbine/power generation components, 4% from transformers, and 19% from turbine transformers.

The use of copper significantly increases when going offshore. That’s because onshore wind farms use approximately 7,766 lbs of copper per MW, while an offshore wind installation uses 21,068 lbs of copper per MW.

It is the cabling of the offshore wind farms to connect them to each other and to deliver the power that accounts for the bulk of the copper usage.

Copper in Solar

Solar power systems can contain approximately 5.5 tons of copper per MW. Copper is in the heat exchangers of solar thermal units as well as in the wiring and cabling that transmits the electricity in photovoltaic solar cells.

Navigant Research projects that 262 GW of new solar installations between 2018 and 2027 in North America will require 1.9 billion lbs of copper.

Copper in Energy Storage

There are many ways to store energy, but every method uses copper. For example, a lithium ion battery contains 440 lbs of copper per MW and a flow battery 540 lbs of copper per MW.

Copper wiring and cabling connects renewable power generation with energy storage, while the copper in the switches of transformers help to deliver power at the right voltage.

Across the United States, a total of 5,752 MW of energy capacity has been announced and commissioned.

Copper in Electric Vehicles

Copper is at the heart of the electric vehicle (EV). This is because EVs rely on copper for the motor coil that drives the engine.

The more electric the car, the more copper it needs; a car powered by an internal combustion engine contains roughly 48 lbs, a hybrid needs 88 lbs, and a battery electric vehicle uses 184 lbs.

Additionally, the cabling for charging stations of electric vehicles will be another source of copper demand.

The Copper Future

Advances in technologies create new material demands.

Therefore, it shouldn’t be surprising that the transition to renewables is going to create demand for many minerals – and copper is going to be a critical mineral for the new era of energy.

Automotive

How Much Oil is in an Electric Vehicle?

It is counterintuitive, but electric vehicles are not possible without oil – these petrochemicals bring down the weight of cars to make EVs possible.

Published

8 months ago

May 20, 2019

Nicholas LePan

How Much Oil is in an Electric Vehicle?

When most people think about oil and natural gas, the first thing that comes to mind is the gas in the tank of their car. But there is actually much more to oil’s role, than meets the eye…

Oil, along with natural gas, has hundreds of different uses in a modern vehicle through petrochemicals.

Today’s infographic comes to us from American Fuel & Petrochemicals Manufacturers, and covers why oil is a critical material in making the EV revolution possible.

Pliable Properties

It turns out the many everyday materials we rely on from synthetic rubber to plastics to lubricants all come from petrochemicals.

The use of various polymers and plastics has several advantages for manufacturers and consumers:

Lightweight
Inexpensive
Plentiful
Easy to Shape
Durable
Flame Retardant

Today, plastics can make up to 50% of a vehicle’s volume but only 10% of its weight. These plastics can be as strong as steel, but light enough to save on fuel and still maintain structural integrity.

This was not always the case, as oil’s use has evolved and grown over time.

Not Your Granddaddy’s Caddy

Plastics were not always a critical material in auto manufacturing industry, but over time plastics such as polypropylene and polyurethane became indispensable in the production of cars.

Rolls Royce was one of the first car manufacturers to boast about the use of plastics in its car interior. Over time, plastics have evolved into a critical material for reducing the overall weight of vehicles, allowing for more power and conveniences.

Timeline:

1916
Rolls Royce uses phenol formaldehyde resin in its car interiors
1941
Henry Ford experiments with an “all-plastic” car
1960
About 20 lbs. of plastics is used in the average car
1970
Manufacturers begin using plastic for interior decorations
1980
Headlights, bumpers, fenders and tailgates become plastic
2000
Engineered polymers first appear in semi-structural parts of the vehicle
Present
The average car uses over 1000 plastic parts

Electric Dreams: Petrochemicals for EV Innovation

Plastics and other materials made using petrochemicals make vehicles more efficient by reducing a vehicle’s weight, and this comes at a very reasonable cost.

For every 10% in weight reduction, the fuel economy of a car improves roughly 5% to 7%. EV’s need to achieve weight reductions because the battery packs that power them can weigh over 1000 lbs, requiring more power.

Today, plastics and polymers are used for hundreds of individual parts in an electric vehicle.

Oil and the EV Future

Oil is most known as a source of fuel, but petrochemicals also have many other useful physical properties.

In fact, petrochemicals will play a critical role in the mass adoption of electric vehicles by reducing their weight and improving their ranges and efficiency. In According to IHS Chemical, the average car will use 775 lbs of plastic by 2020.

Although it seems counterintuitive, petrochemicals derived from oil and natural gas make the major advancements by today’s EVs possible – and the continued use of petrochemicals will mean that both EVS and traditional vehicles will become even lighter, faster, and more efficient.